Beilstein J. Org. Chem.2013,9, 1397–1406, doi:10.3762/bjoc.9.156
proposed.
Keywords: copper(II) salt; cyclopropanol; electron transfer; free radical; radicalionprobe; Introduction
Radical ions are key intermediates in electron-transfer (ET) reactions of organic molecules [1][2][3][4][5] and they often undergo fragmentations to yield free radicals and ions [6][7][8
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Graphical Abstract
Scheme 1:
Comparison of fragmentation reaction pathways of organic radical ions generated under the redox-rea...